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Adding the following code snippets to your Multisite wp-config.php will allow the specific plugin to function properly when Network Activated.
Akismet
/** Define WordPress.com API Key */ define('WPCOM_API_KEY','9ab1da1a259d');
Backup Buddy
/* Network Integration for Backup Buddy */ define( 'PB_BACKUPBUDDY_MULTISITE_EXPERIMENT', true );
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